Estimating the seasonal impact of optically significant water constituentson surface heating rates in the western Baltic Sea

Heating rates induced by optically significant water constituents (OSCs), e.g. phytoplankton and coloured dissolved organic matter (CDOM), contribute to the seasonal modulation of thermal energy fluxes across the ocean-atmosphere interface in coastal and regional shelf seas. This is investigated in the western Baltic Sea, a marginal sea characterised by considerable inputs of freshwater carrying nutrients and CDOM and by complex bio-optical and hydrodynamic processes. Using a coupled bio-optical ocean model (ROMS-Bio-Optic), the inherent optical properties of different OSCs are modelled under varying environmental conditions, and the underwater light field is spectrally resolved in a dynamic ocean. We estimate the relative contribution of these OSCs to the divergence of the heat flux and heating rates and find that, while phytoplankton and CDOM both contribute to surface heating in summer, phytoplankton dominates the OSC contribution to heating in spring, and CDOM dominates the OSC contribution to heating in autumn. The study shows that seasonal and spatial changes in OSCs in the western Baltic Sea have a small but noticeable impact on radiative heating in surface waters and consequences for the exchange of energy fluxes across the air-sea interface and the distribution of heat within the water column. In the Pomeranian Bight, where riverine influx of CDOM is strongest, water-constituent-induced heating rates in surface waters in 2018 are estimated to be between 0.8 and 0.9 Km(-1) d(-1) in spring and summer, predominantly as a result of increased absorption by phytoplankton and CDOM. Further offshore, OSC-induced heating rates during the same periods are estimated to be between 0.4 and 0.8 Km(-1) d(-1). Warmer surface waters are balanced by cooler subsurface waters. Surface heat fluxes (latent, sensible and longwave) respond to warmer sea surface temperatures, with a small increase in heat loss to the atmosphere of 5 Wm(-2) during the period April to September. We find relatively good agreement between our modelled water constituent absorption and in situ and satellite observations. More rigorous co-located heating-rate calculations using an atmosphere-ocean radiative transfer model provide evidence of the suitability of the ROMS-Bio-Optic model for estimating heating rates.