Spontaneous Dipole Reorientation in Confined Water and Its Effect on Wetting/Dewetting of Hydrophobic Nanopores.

The properties of nanoconfined fluids are important for a broad range of natural and engineering systems. In particular, wetting/dewetting of hydrophobic nanoporous materials is crucial due to their broad applicability for molecular separation and liquid purification; energy storage, conversion, recuperation, and dissipation; for catalysis, chromatography, and so on. In this work, a rapid, orchestrated, and spontaneous dipole reorientation was observed in hydrophobic nanotubes of various pore sizes d (7.9-16.5 Å) via simulations. This phenomenon leads to the fragmentation of water clusters in the narrow nanopores (d = 7.9, 10 Å) and strongly affects dewetting through cluster repulsion. The cavitation in these pores has an electrostatic origin. The dependence of hydrogen-bonded network properties on the tube aperture is obtained and is used to explain wetting (intrusion)-dewetting (extrusion) hysteresis. Computer simulations and experimental data demonstrate that d equals ca. 12.5 Å is a threshold between a nonhysteretic (spring) behavior, where intrusion-extrusion is reversible, and a hysteretic one (shock absorber), where hysteresis is prominent. This work suggests that water clustering and the electrostatic nature of cavitation are important factors that can be effectively exploited for controlling the wetting/dewetting of nanoporous materials.